宿主葫芦[7]脲与含有单个二茂铁基残基的树枝状大分子客体之间的结合相互作用。
Binding interactions between the host cucurbit[7]uril and dendrimer guests containing a single ferrocenyl residue.
作者信息
Sobransingh David, Kaifer Angel E
机构信息
Center for Supramolecular Science and Department of Chemistry, University of Miami, Coral Gables, FL 33124-0431, USA.
出版信息
Chem Commun (Camb). 2005 Oct 28(40):5071-3. doi: 10.1039/b510780f. Epub 2005 Sep 13.
DOI:10.1039/b510780f
PMID:16220174
Abstract
The stability of the inclusion complexes formed between the host cucurbit[7]uril and dendrimers containing a single ferrocene residue is strongly affected by the solution pH and the growth of the dendrimer, reaching its highest values on the second and third generation dendrimers, whereas no complex is formed with the first generation compound.
摘要
主体葫芦[7]脲与含有单个二茂铁残基的树枝状大分子形成的包合物的稳定性受溶液pH值和树枝状大分子生长的强烈影响，在第二代和第三代树枝状大分子上达到最高值，而第一代化合物不形成复合物。
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