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外向双酰胺主体与双（铵）客体络合时构象的立体专一性变化：手性识别与强圆二色信号

Stereospecific change in conformation upon complexation of an exoditopic tetraamide host with a bis(ammonium) guest: chiral recognition and strong CD signaling.

作者信息

Katoono Ryo, Kawai Hidetoshi, Fujiwara Kenshu, Suzuki Takanori

机构信息

Division of Chemistry, Graduate School of Science, Hokkaido University, Sapporo 060-0810, Japan.

出版信息

Chem Commun (Camb). 2005 Nov 7(41):5154-6. doi: 10.1039/b510134d. Epub 2005 Sep 13.

DOI:10.1039/b510134d
PMID:16228019
Abstract

Upon complexation of a rectangular-shaped achiral macrocyclic host with chiral guests, twisting deformation occurs to induce exciton-type bisignated CD, whereas a chiral rectangular host undergoes a similar structural change only with the matching enantiomer of a chiral guest.

摘要

当矩形非手性大环主体与手性客体络合时，会发生扭曲变形以诱导激子型双信号圆二色性，而手性矩形主体仅与手性客体的匹配对映体发生类似的结构变化。

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