硅氢化反应中Stryker试剂的一种新替代物：一种明确的卡宾-醋酸铜（II）配合物的合成、结构及反应活性
A new alternative to Stryker's reagent in hydrosilylation: synthesis, structure, and reactivity of a well-defined carbene-copper(II) acetate complex.
作者信息
Yun Jaesook, Kim Daesung, Yun Hoseop
机构信息
Department of Chemistry and Institute of Basic Sciences, Sungkyunkwan University, Suwon 440-746, Korea.
出版信息
Chem Commun (Camb). 2005 Nov 7(41):5181-3. doi: 10.1039/b509964a. Epub 2005 Sep 22.
DOI:10.1039/b509964a
PMID:16228028
Abstract
A new, air stable and well-defined carbene-copper(II) complex has been prepared, which is an efficient precatalyst for the 1,2- and 1,4-reduction of carbonyl compounds under hydrosilylation conditions.
摘要
一种新型的、对空气稳定且结构明确的卡宾-铜（II）配合物已被制备出来，它是在硅氢化条件下用于羰基化合物1,2-还原和1,4-还原的高效前催化剂。
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