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独特的自组装二维金属四唑酸盐网络：[M(pmtz)₂](M = Co(II)和Fe(II); Hpmtz = 5-(嘧啶基)四唑)的晶体结构和磁性

Unique self-assembled 2D metal-tetrazolate networks: crystal structure and magnetic properties of [M(pmtz)2](M = Co(II) and Fe(II); Hpmtz = 5-(pyrimidyl)tetrazole).

作者信息

Rodríguez Antonio, Kivekäs Raikko, Colacio Enrique

机构信息

Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Granada, E-18071 Granada, Spain.

出版信息

Chem Commun (Camb). 2005 Nov 7(41):5228-30. doi: 10.1039/b509069e. Epub 2005 Sep 22.

DOI:10.1039/b509069e
PMID:16228044
Abstract

The title compounds, which have been prepared from M(II) salts (M = Co and Fe) and 5-(pyrimidyl)tetrazole under hydrothermal conditions, are isomorphous and exhibit a 2D square-grid-like structure; the cobalt complex is a spin-canted antiferromagnet with Tc= 15 K.

摘要

通过水热条件下由M（II）盐（M = Co和Fe）与5-（嘧啶基）四唑制备得到的标题化合物是同构的，并且呈现出二维方格状结构；钴配合物是一种自旋倾斜反铁磁体，居里温度Tc = 15 K。

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