Nanostructuring and nanoanalysis by scanning electrochemical microscopy (SECM).

The generation and application of nanodes in SECM experiments are described. Nanodes are ultramicroelectrodes with an active disk diameter in the submicrometer range. We investigated the behaviour of these electrodes by testing their properties with SECM applications which were previously performed at the micrometer scale. The active diameter of the nanodes was determined using cyclic voltammetry and SECM. The nanoanalysis was conducted at two nano interdigitated arrays. The nanostructuring was demonstrated by galvanic and electroless silver deposition from solution and from the surface, respectively. Experiments with nanodes illustrate that they exhibit the same behaviour as ultramicroelectrodes, but are more sensitive to adsorption and dirt particles in the electrolyte solution.