带有金属配位基团的锰卟啉对甾体进行区域选择性氧化。
Regioselective oxidation of steroids by a manganese porphyrin carrying metal coordinating groups.
作者信息
Belvedere S, Breslow R
机构信息
Department of Chemistry, Columbia University, New York, New York 10027, USA.
出版信息
Bioorg Chem. 2001 Oct;29(5):321-31. doi: 10.1006/bioo.2001.1215.
PMID:16256701
Abstract
A manganese porphyrin having four 2,2'-bipyridyl groups on its meso positions was synthesized. In the presence of Cu2+ ions it catalyzes the regioselective oxidation of steroid substrates carrying auxiliary metal coordinating groups.
摘要
合成了一种在其中位具有四个2,2'-联吡啶基团的锰卟啉。在Cu2+离子存在下，它催化带有辅助金属配位基团的甾体底物的区域选择性氧化。
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