Belvedere S, Breslow R
Department of Chemistry, Columbia University, New York, New York 10027, USA.
Bioorg Chem. 2001 Oct;29(5):321-31. doi: 10.1006/bioo.2001.1215.
A manganese porphyrin having four 2,2'-bipyridyl groups on its meso positions was synthesized. In the presence of Cu2+ ions it catalyzes the regioselective oxidation of steroid substrates carrying auxiliary metal coordinating groups.
合成了一种在其中位具有四个2,2'-联吡啶基团的锰卟啉。在Cu2+离子存在下，它催化带有辅助金属配位基团的甾体底物的区域选择性氧化。
Zotero 插件