Ling Wen, Jerschow Alexej
Department of Chemistry, New York University, 100 Washington Square East, New York, NY 10003, USA.
Solid State Nucl Magn Reson. 2006 Feb;29(1-3):227-31. doi: 10.1016/j.ssnmr.2005.09.012. Epub 2005 Oct 28.
A method for the selective detection of quadrupolar nuclei located in anisotropic environments is presented. The image contrast can be tuned to the degree of anisotropy in the sample by using frequency-swept pulsed. These methods are particularly useful in the field of sodium-MRI, where sodium signals from locally-ordered environments provide diagnostic information. In solid-state MRI, these methods could be useful for probing structural defects within the sample. We demonstrate here one-dimensional images, in which the pixel contrast indicates the presence or absence of quadrupolar coupling within a certain frequency range.
本文提出了一种用于选择性检测处于各向异性环境中的四极核的方法。通过使用频率扫描脉冲,图像对比度可根据样品中的各向异性程度进行调整。这些方法在钠磁共振成像领域特别有用,其中来自局部有序环境的钠信号可提供诊断信息。在固态磁共振成像中,这些方法可用于探测样品内部的结构缺陷。我们在此展示了一维图像,其中像素对比度表明在特定频率范围内是否存在四极耦合。