Fouchet Julien, Jeandon Christophe, Ruppert Romain, Callot Henry J
U.M.R. 7177 du C.N.R.S., Faculté de Chimie, Université Louis Pasteur, 1, Rue Blaise Pascal, F-67000 Strasbourg, France.
Org Lett. 2005 Nov 10;7(23):5257-60. doi: 10.1021/ol052103y.
[reaction: see text] Upon tandem Reformatsky reaction, easily accessible porphyrinic ketones give "locked" chlorinic diester. Both ketones and diesters, as bases or palladium complexes, efficiently generate singlet dioxygen, as demonstrated by trapping with cholesterol.
[反应：见正文] 通过串联Reformatsky反应，易于获得的卟啉酮可生成“锁定”的二氢卟吩二酯。酮类和二酯类作为碱或钯配合物，能有效地生成单线态氧，这通过用胆固醇捕获得以证明。
