Highly selective two-photon chemosensors for fluoride derived from organic boranes.
作者信息
Liu Zhi-Qiang, Shi Mei, Li Fu-You, Fang Qi, Chen Zhang-Hai, Yi Tao, Huang Chun-Hui
机构信息
Laboratory of Advanced Materials, Fudan University, 200433 Shanghai, PR China.
出版信息
Org Lett. 2005 Nov 24;7(24):5481-4. doi: 10.1021/ol052323b.
PMID:16288536
Abstract
[reaction: see text] Three organoboron compounds are shown to be two-photon fluorescent sensors for fluoride anion with high sensitivity and selectivity. The recognition mechanism is attributed to the unique steric structure of the bulky dimesitylboryl group and the Lewis acid-base interaction between trivalent boron atom and fluoride anion.
摘要
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