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利用荧光光谱法对阳离子双尾表面活性剂与磷脂混合胶束的表征

Characterization of mixed micelles of cationic twin tail surfactants with phospholipids using fluorescence spectroscopy.

作者信息

Bakshi Mandeep Singh, Singh Kulbir, Singh Jasmeet

机构信息

Department of Chemistry, Guru Nanak Dev University, Amritsar 143005, Punjab, India.

出版信息

J Colloid Interface Sci. 2006 May 1;297(1):284-91. doi: 10.1016/j.jcis.2005.10.034. Epub 2005 Nov 11.

DOI:10.1016/j.jcis.2005.10.034
PMID:16289191
Abstract

The pyrene fluorescence measurements have been carried out for various binary mixtures of micelle forming (L-alpha-diheptanoylphosphatidycholine, DHPC) and vesicle forming (L-alpha-dimyristoylphosphatidycholine, DMPC) phospholipids with different twin tail alkylammonium surfactants. The mixed micelle formation in all binary mixtures has been evaluated and it has been observed that the mixed micelle formation between the unlike components of phospholipid and cationic surfactants takes place due to the synergistic interactions. The influence of hydrophobicity of series of twin tail cationic surfactants has been studied on the degree of synergism.

摘要

已对胶束形成剂(L-α-二庚酰磷脂酰胆碱,DHPC)和囊泡形成剂(L-α-二肉豆蔻酰磷脂酰胆碱,DMPC)磷脂与不同双尾烷基铵表面活性剂的各种二元混合物进行了芘荧光测量。已评估了所有二元混合物中的混合胶束形成情况,并且观察到磷脂和阳离子表面活性剂不同组分之间的混合胶束形成是由于协同相互作用而发生的。研究了一系列双尾阳离子表面活性剂的疏水性对协同程度的影响。

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