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液滴在饱和多孔层上的铺展。

Spreading of liquid drops over saturated porous layers.

作者信息

Starov V M, Kosvintsev S R, Sobolev V D, Velarde M G, Zhdanov S A

机构信息

Department of Chemical Engineering, Loughborough University, Loughborough, Leicestershire LE11 3TU, United Kingdom.

出版信息

J Colloid Interface Sci. 2002 Feb 15;246(2):372-9. doi: 10.1006/jcis.2001.8077.

Abstract

Spreading of small liquid drops over thin porous layers saturated with the same liquid is investigated from both theoretical and experimental points of view. A theory is presented that shows that spreading is governed by the same power law as in the case of spreading over a dry solid substrate. The Brinkman's equations are used to model the liquid flow inside the porous substrate. An equation of the drop spreading is deduced, which shows that both an effective lubrication and the liquid exchange between the drop and the porous substrates are equally important. The presence of these two phenomena removes the well-known singularity at the moving three-phase contact line. Matching of the drop profile in the vicinity of the three-phase contact line with the main spherical part of the drop gives the possibility to calculate the pre-exponential factor in the spreading law via permeability and effective viscosity of the liquid in the porous layer. Unfortunately, the latter dependency turns out to be very weak. Spreading of silicone oils over different microfiltration membranes is carried out. Radii of spreading on time experimental dependencies confirm the theory predictions. Experimentally found coefficients agree with theoretical estimations.

摘要

从理论和实验两个角度研究了小液滴在充满相同液体的薄多孔层上的铺展情况。提出了一种理论,该理论表明铺展遵循与在干燥固体基质上铺展相同的幂律。使用布林克曼方程对多孔基质内部的液体流动进行建模。推导了液滴铺展方程,该方程表明有效润滑以及液滴与多孔基质之间的液体交换同样重要。这两种现象的存在消除了移动三相接触线上众所周知的奇点。通过将三相接触线附近的液滴轮廓与液滴的主要球形部分进行匹配,有可能通过多孔层中液体的渗透率和有效粘度来计算铺展定律中的指数前因子。不幸的是,后者的依赖性非常弱。进行了硅油在不同微滤膜上的铺展实验。铺展半径随时间的实验依赖性证实了理论预测。实验得到的系数与理论估计值相符。

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