Assessment of small-angle and angle-averaged structure factor for monitoring electrostatic colloidal interactions using multiply scattered light.

The isotropic scattering coefficients of 143-nm diameter polystyrene latex suspensions were measured using frequency-domain photon migration (FDPM) at 687 and 828 nm as a function of volume fraction (0.05-0.3) and ionic strength (1.0 to 120 mM NaCl equivalents) in order to derive the angle-integrated structure factor, S(q), and structure factor at zero wave vector, S(0). The effective surface charges of the dispersions were estimated by fitting the measured isotropic scattering coefficients at each wavelength as a function of volume fraction to the solution of the Orstein-Zernike integral equation using the hard sphere Yukawa potential model and mean spherical approximation as a closure relation. The estimates of surface charges were comparable at both wavelengths, but decreased with ionic strength. At 120 mM NaCl equivalents, the values of S(0) obtained from FDPM matched those predicted by the Percus-Yevick model, and decreased with volume fraction, consistent with prediction by the Carnahan-Starling equation.