Metals in soils of children's urban environments in the small northern European city of Uppsala.

Metals occur naturally in soil, but contents are generally increased in the urban environment due to anthropogenic activities. The presence of elevated metals in soils of the urban environment has been recognized as an important source of metal intake in children and is linked to elevated metal levels in children's blood. Several metals have undesirable health effects, especially on children due to their still developing nervous system and small body volumes. Playgrounds are where urban children spend most of their time outdoors and are also where children most frequently come in contact with soil. Elevated contents of metals in playgrounds are therefore of great concern for children's wellbeing. This study investigates the soil metal content of 25 playgrounds located in different land use areas in urban Uppsala, Sweden's fourth largest city. Uppsala covers an area of approximately 100 km2 and has a population of 136,000. The soil samples were analysed for 12 metals (Al, As, Cd, Cr, Cu, Fe, Hg, Mn, Ni, Pb, W, Zn) using aqua regia. Median metal contents were found to be 1.8, 3.4, 0.21, 32, 25, 2.5, 0.14, 494, 19, 26, 0.35 and 84 mg kg(-1) soil for each of the above metals, respectively. The median clay content was around 20% while the organic matter content was measured by loss on ignition at a median of 8%. The land use areas included industrial land, the city center, road verges, natural land and former industrial land. The results showed that land use did not have the expected large influence on the total metal contents of the soils tested. The clay content together with the age of the site proved to be a more important factor. Sites with elevated clay contents had in general elevated metal contents, which were explained by the relatively high adsorption capacity of clay particles. The soils at sites where land use had not been altered since the 1800s had increased metal contents compared to playgrounds constructed in the late 1900s. The immobility of metals once they had entered the soil system was the reason for increased metal content in soils of old playgrounds. It was concluded that in cities with few internal pollution sources, the soil characteristics of the site and the time the soil has been on-site to accumulate metal residues become important factors in determining the soil metal content.