The Potential Environmental Impact of PAHs on Soil and Water Resources in Air Deposited Coal Refuse Sites in Niangziguan Karst Catchment, Northern China.

Long-term deposition of coal spoil piles may lead to serious pollution of soil and water resources in the dumping sites and surrounding areas. Karst aquifers are highly sensitive to environmental pollution. In this study, the occurrence and release/mobilization of polycyclic aromatic hydrocarbons (PAHs) in coal waste and coal spoils fire gas mineral (CSFGM) were evaluated by field and indoor investigations at Yangquan city, one of the major coal mining districts in the karst areas of northern China. Field investigations showed that dumping of coal waste over decades has resulted in soil and water pollution via spontaneous combustion and leaching of coal spoil piles. Indoor analysis revealed that the 2-ring and 3-ring PAHs contribute to 65-80% of the total PAHs in coal spoils, with naphthalene (Nap), Chrysene (Chr), and Phenanthrene (Phe) as the dominant compounds. Based on a heating/burning simulation experiment, the production of PAHs is temperature-dependent and mainly consists of low-ring PAHs: 2-ring, 3-ring, and part of the 4-ring PAHs. The PAHs in the leachate are light-PAHs (Nap, 20.06 ng/L; Phe, 4.76 ng/L) with few heavy-PAHs. The distribution modes of PAHs in two soil profiles suggest that the precipitation caused downward movement of PAHs and higher mobility of light-PAHs.