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磷酸和硫酸溶液中的移动单泡声致发光

Moving single bubble sonoluminescence in phosphoric acid and sulphuric acid solutions.

作者信息

Troia A, Ripa D Madonna, Spagnolo R

机构信息

Istituto Elettrotecnico Nazionale Galileo Ferraris, Acoustics Department, Strada delle Cacce 91, 10135 Turin, Italy.

出版信息

Ultrason Sonochem. 2006 Apr;13(3):278-82. doi: 10.1016/j.ultsonch.2005.06.002. Epub 2005 Nov 23.

Abstract

The phenomenon of sonoluminescence still presents some unsolved aspects. Recently [Y.T. Didenko, K. Suslick, Molecular Emission during Single Bubble Sonoluminescence, Nature 407 (2000) 877-879.], it was found that a single cavitating air bubble in polar aprotic liquids (including formamide and adiponitrile) can produce very strong sonoluminescence while undergoing macroscopic translation movements in the resonator, a condition known as moving single bubble sonoluminescing (MSBSL). Here we describe some experiments conducted in aqueous solutions of phosphoric and sulphuric acid. In these liquid media, it is possible to reproduce MSBSL and luminescence is emitted even if a trapped bubble is subjected to a strong shape instability, named in the literature "jittering phase". When a moving and luminescing bubble was present and the acoustic pressure gradually increased, we observed the generation of a discrete lattice of trapped bubbles. The bubbles in the lattice emit very intense light flashes and can change their position while maintaining the overall spatial distribution in time. Some preliminary results, obtained from Mie-scattering and measurements of relative light intensity, are reported.

摘要

声致发光现象仍然存在一些尚未解决的方面。最近[Y.T. 迪登科、K. 苏斯利克,《单泡声致发光过程中的分子发射》,《自然》407 (2000) 877 - 879],发现极性非质子液体(包括甲酰胺和己二腈)中的单个空化气泡在谐振器中进行宏观平移运动时会产生非常强烈的声致发光,这种情况被称为移动单泡声致发光(MSBSL)。在此,我们描述了在磷酸和硫酸水溶液中进行的一些实验。在这些液体介质中,即使捕获的气泡受到强烈的形状不稳定性(文献中称为“抖动阶段”),也有可能重现MSBSL并发射光。当存在一个移动且发光的气泡且声压逐渐增加时,我们观察到了捕获气泡的离散晶格的产生。晶格中的气泡会发出非常强烈的闪光,并且在保持整体空间分布随时间不变的同时可以改变其位置。报告了从米氏散射和相对光强测量中获得的一些初步结果。

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