Li Fang-Fang, Ma Jian-Fang, Song Shu-Yan, Yang Jin, Liu Ying-Ying, Su Zhong-Min
Department of Chemistry, Northeast Normal University, Changchun 130024, People's Republic of China.
Inorg Chem. 2005 Dec 12;44(25):9374-83. doi: 10.1021/ic050984z.
This article represents a systematical examination of the structures of silver(I) sulfonates incorporating neutral ligands. To survey the influence of the properties of neutral ligands on the structures of silver(I) sulfonates, three kinds of sulfonate anions (L1=1-naphthalenesulfonate, L2=p-toluenesulfonate, and L3=1, 3, 6, 8-pyrenetetrasulfonate) and three kinds of neutral ligands (pyrazine, Pyr, a divergent bidentate ligand; hexamethylenetetramine, hmt, a divergent tetradentate ligand; and beta-picoline, Pic, a monodentate ligand) were selected for study, and five novel silver(I) sulfonates containing neutral ligands have been synthesized: [Ag(L1)(Pyr)].H2O, Ag(L2)(Pyr), Ag4(L3)(Pyr)4(H2O)2, [Ag(L1)(hmt)].H2O, and Ag(L1)(Pic)2. The crystal structures have been determined by single-crystal X-ray diffraction, and these compounds show a variety of structures with different dimensionalities. Moreover, the luminescent properties of compounds and are also discussed.
本文对含中性配体的磺酸银（I）的结构进行了系统研究。为了探究中性配体性质对磺酸银（I）结构的影响，选取了三种磺酸根阴离子（L1 = 1 - 萘磺酸根、L2 = 对甲苯磺酸根、L3 = 1, 3, 6, 8 - 芘四磺酸根）和三种中性配体（吡嗪，Pyr，一种发散型双齿配体；六亚甲基四胺，hmt，一种发散型四齿配体；以及β - 甲基吡啶，Pic，一种单齿配体）进行研究，并合成了五种含中性配体的新型磺酸银（I）：[Ag(L1)(Pyr)].H2O、Ag(L2)(Pyr)、Ag4(L3)(Pyr)4(H2O)2、[Ag(L1)(hmt)].H2O和Ag(L1)(Pic)2。通过单晶X射线衍射测定了晶体结构，这些化合物呈现出多种不同维度的结构。此外，还讨论了这些化合物的发光性质。
