Nagarale R K, Gohil G S, Shahi Vinod K
Central Salt and Marine Chemicals Research Institute, Bhavnagar-364002, Gujarat, India.
Adv Colloid Interface Sci. 2006 Feb 28;119(2-3):97-130. doi: 10.1016/j.cis.2005.09.005. Epub 2005 Dec 2.
Rapid growth of chemical and biotechnology in diversified areas fuels the demand for the need of reliable green technologies for the down stream processes, which include separation, purification and isolation of the molecules. Ion-exchange membrane technologies are non-hazardous in nature and being widely used not only for separation and purification but their application also extended towards energy conversion devices, storage batteries and sensors etc. Now there is a quite demand for the ion-exchange membrane with better selectivities, less electrical resistance, high chemical, mechanical and thermal stability as well as good durability. A lot of work has been done for the development of these types of ion-exchange membranes during the past twenty-five years. Herein we have reviewed the preparation of various types of ion-exchange membranes, their characterization and applications for different electro-membrane processes. Primary attention has been given to the chemical route used for the membrane preparation. Several general reactions used for the preparation of ion-exchange membranes were described. Methodologies used for the characterization of these membranes and their applications were also reviewed for the benefit of readers, so that they can get all information about the ion-exchange membranes at one platform. Although there are large number of reports available regarding preparations and applications of ion-exchange membranes more emphasis were predicted for the usefulness of these membranes or processes for solving certain type of industrial or social problems. More efforts are needed to bring many products or processes to pilot scale and extent their applications.
化学和生物技术在多个领域的快速发展,推动了对下游工艺可靠绿色技术的需求,这些下游工艺包括分子的分离、纯化和分离。离子交换膜技术本质上是无害的,不仅广泛用于分离和纯化,其应用还扩展到能量转换装置、蓄电池和传感器等领域。现在,对具有更好选择性、更低电阻、高化学、机械和热稳定性以及良好耐久性的离子交换膜有相当大的需求。在过去二十五年中,为开发这类离子交换膜做了大量工作。在此,我们综述了各类离子交换膜的制备、表征及其在不同电膜过程中的应用。主要关注了用于膜制备的化学路线。描述了用于制备离子交换膜的几种一般反应。还综述了用于表征这些膜及其应用的方法,以便读者受益,使他们能够在一个平台上获取有关离子交换膜的所有信息。尽管有大量关于离子交换膜制备和应用的报告,但预计更多强调这些膜或工艺对解决某些类型的工业或社会问题的有用性。需要做出更多努力,使许多产品或工艺达到中试规模并扩大其应用。