Baran Ayşe, Baysal Senay Hamarat, Sukatar Atakan
Biochemistry Department, Ege University, Faculty of Science, Bornova, Izmir, Turkey.
J Environ Biol. 2005 Jun;26(2 Suppl):329-33.
Biosorption of Cr6+ from aqueous solution on dried (Halimeda tuna, Sargassum vulgare, Pterocladia capillacea, Hypnea musciformis, Laurencia papillosa) algae were studied with variation in the parameters of pH, initial metal ion concentration and agitation time. From the batch system studies the working sorption pH value was determined as 1.0 for Halimeda tuna and Sargassum vulgare, 2.0 for Pterocladia capillacea and Hypnea musciformis, 3.0 for Laurencia papillosa. The total adsorbed quantities, equilibrium uptakes and total removal percents of Cr6+ were determined by evaluating the breakthrough curves obtained at different inlet Cr6+ concentration for each sorbent. The maximum chromium biosorption occured at 120 min for Halimeda tuna, 180 min for Sargassum vulgare, Hypnea musciformis and Pterocladia capillacea, 60 min for Laurencia papillosa. The suitability of the Freundlich and Langmiur adsorption models were also investigated for each chromium-sorbent system. The results showed that Sargassum vulgare was found suitable for removing chromium from aqueous solution. The maximum sorption capacities of Halimeda tuna, Sargassum vulgare, Pterocladia capillacea, Hypnea musciformis, Laurencia papillosa were determined as 2.3, 33.0, 6.6, 4.7 and 5.3 mgg(-1).
研究了干燥的(仙掌藻、羊栖菜、鹿角菜、鼠尾藻、乳头藻)藻类对水溶液中Cr6+的生物吸附,考察了pH值、初始金属离子浓度和搅拌时间等参数的变化。通过间歇系统研究,确定了仙掌藻和羊栖菜的工作吸附pH值为1.0,鹿角菜和鼠尾藻为2.0,乳头藻为3.0。通过评估每种吸附剂在不同入口Cr6+浓度下获得的穿透曲线,确定了Cr6+的总吸附量、平衡吸附量和总去除率。仙掌藻在120分钟时达到最大铬生物吸附量,羊栖菜、鼠尾藻和鹿角菜在180分钟时达到最大铬生物吸附量,乳头藻在60分钟时达到最大铬生物吸附量。还研究了Freundlich和Langmiur吸附模型对每个铬-吸附剂系统的适用性。结果表明,羊栖菜适合从水溶液中去除铬。仙掌藻、羊栖菜、鹿角菜、鼠尾藻、乳头藻的最大吸附容量分别为2.3、33.0、6.6、4.7和5.3 mgg(-1)。