Gioia Francesco, Urciuolo Massimo
Dipartimento di Ingegneria Chimica, Università di Napoli Federico II, Piazzale Tecchio, Italy.
J Hazard Mater. 2006 May 20;133(1-3):218-25. doi: 10.1016/j.jhazmat.2005.10.010. Epub 2005 Dec 15.
The mobilization of an oil bank under the combined effect of Bond (N(B)) and capillary (N(C)) numbers, in a packed bed column of glass beads saturated with water, has been investigated. In order to reach the irreducible saturation the experiments have been run with sweeping water velocities outside the range of validity of the Darcy's law. The size of the glass beads was varied in the range between 2 mm and 5 mm. The oils used for the tests are hexadecane and hexane with viscosities different for an order of magnitude and densities smaller than that of water, and alpha-methylnaphthalene, which has a density very close to that of water, in order to single out the effect of the capillary number on the mobilization process. The plots of oil saturation as function of the trapping number (N(T)), which is the vectorial sum of N(B) and N(C), are reported and a mobilization diagram is drawn. Furthermore, a few tests in a basin, simulating an aquifer at a laboratory scale, have proved that the results obtained in the packed column are useful for determining the fate of a spill of oil above an aquifer. For these experiments also perchloroethylene (PCE), which has a density greater than that of water, has been used.
在充满水的玻璃珠填充床柱中,研究了在邦德数(N(B))和毛细管数(N(C))共同作用下油藏的动用情况。为了达到残余饱和度,实验在超出达西定律有效性范围的扫水速度下进行。玻璃珠的尺寸在2毫米至5毫米之间变化。用于测试的油有十六烷和己烷,它们的粘度相差一个数量级且密度小于水,还有α-甲基萘,其密度与水非常接近,以便单独研究毛细管数对动用过程的影响。报告了油饱和度与捕集数(N(T))(N(B)和N(C)的矢量和)的关系图,并绘制了动用图。此外,在一个模拟实验室规模含水层的水池中进行的一些测试证明,在填充柱中获得的结果对于确定含水层上方油泄漏的归宿是有用的。对于这些实验,还使用了密度大于水的全氯乙烯(PCE)。