Lyle Michael P A, Wilson Peter D
Department of Chemistry, Simon Fraser University, 8888 University Drive, Burnaby, British Columbia, Canada V5A 1S6.
Org Biomol Chem. 2006 Jan 7;4(1):41-3. doi: 10.1039/b513374m. Epub 2005 Nov 24.
The evaluation of a chiral, nonracemic and C2-symmetric 2,2'-bipyridyl ligand in copper(I)-catalyzed asymmetric allylic oxidation reactions of a series of cyclic alkenes with tert-butyl peroxybenzoate is reported (up to 91% ee, the highest reported enantioselectivity for a bipyridyl ligand copper(I) complex to date).
报道了一种手性、非外消旋且具有C2对称性的2,2'-联吡啶配体在铜（I）催化一系列环状烯烃与叔丁基过氧苯甲酸酯的不对称烯丙基氧化反应中的应用（对映体过量值高达91%，这是迄今为止报道的联吡啶配体铜（I）配合物的最高对映选择性）。
