Cui Fu-Yi, Wu Ya-Qin, Liu Dong-Mei, Zhang Min
School of Municipal & Environmental Engineering, Harbin Institute of Technology, Harbin 150090, China.
Huan Jing Ke Xue. 2005 Sep;26(5):89-94.
The inactivation effects of ozone, hydrogen peroxide, O3/H2O2 processes on Cyclops of zooplankton were discussed. It was found that O3/H2O2 possessed more favorable inactivation effect on Cyclops compared with the others, in distilled water with 1.0 mg/L of O3 and 4 mg/L of H2O2 the inactivation effect was 100% after 30 min contacting; ozone also had favorable inactivation effect, the inactivation effect is 80% by 1.0 mg/L of ozone alone; while hydrogen peroxide didn't, there was almost no inactivation effect by 4 mg/L of H2O2. The best inactivation condition for O3/H2O2 processes, that was, two oxidants were added sequentially with interval in range of 30 to 60 seconds, for them ozone at first. And the influencing factors under various conditions such as the dose of hydrogen peroxide, organic substance content, pH value, etc. were researched and reported. It was found that the effect didn't changed largely with H2O2 on the range of 4 mg/L to 10 mg/L, and inactivation effects on Cyclops of O3/H2O2 were not sensitive to pH value, while it declined obviously as the organic content increased. Finally, synergic removal effect on Cyclops with O3/H2O2 preoxidation followed by clarification process was investigated. The results show that the removal effect on Cyclops is further strengthened by clarification processes after O3/H2O2 pre-oxidation.
讨论了臭氧、过氧化氢、臭氧/过氧化氢工艺对浮游动物剑水蚤的灭活效果。结果发现,与其他工艺相比,臭氧/过氧化氢对剑水蚤具有更良好的灭活效果,在含有1.0mg/L臭氧和4mg/L过氧化氢的蒸馏水中,接触30分钟后灭活效果达100%;臭氧也有良好的灭活效果,单独使用1.0mg/L臭氧时灭活效果为80%;而过氧化氢则没有,4mg/L过氧化氢几乎没有灭活效果。臭氧/过氧化氢工艺的最佳灭活条件是,两种氧化剂依次添加,间隔时间在30至60秒之间,先添加臭氧。并研究报道了各种条件下如过氧化氢剂量、有机物含量、pH值等的影响因素。结果发现,在4mg/L至10mg/L范围内,过氧化氢对效果影响不大,臭氧/过氧化氢对剑水蚤的灭活效果对pH值不敏感,但随着有机物含量增加明显下降。最后,研究了臭氧/过氧化氢预氧化后再进行澄清工艺对剑水蚤的协同去除效果。结果表明,臭氧/过氧化氢预氧化后再进行澄清工艺对剑水蚤的去除效果进一步增强。