从脱硫脱硫弧菌中分离出的一种新型环状磷化合物的结构测定
Structure determination of a novel cyclic phosphocompound isolated from Desulfovibrio desulfuricans.
作者信息
Turner D L, Santos H, Fareleira P, Pacheco I, LeGall J, Xavier A V
机构信息
Department of Chemistry, University of Southampton, U.K.
出版信息
Biochem J. 1992 Jul 15;285 ( Pt 2)(Pt 2):387-90. doi: 10.1042/bj2850387.
Abstract
The structure of a novel diphosphodiester compound recently detected in Desulfovibrio desulfuricans cells [Santos, Fareleira, Pedregal, LeGall & Xavier (1991) Eur. J. Biochem. 201, 283-287] was fully elucidated using a combination of n.m.r. techniques in aqueous and in methanolic solutions. The novel metabolite was identified as 3-methyl-1,2,3,4-tetrahydroxybutane-1,3-cyclic bisphosphate, and the minimum energy conformation is presented. The two chiral centres have the relative configuration RS.
摘要
最近在脱硫脱硫弧菌细胞中检测到的一种新型二磷酸二酯化合物的结构[桑托斯、法雷莱拉、佩德雷加尔、勒加尔和哈维尔（1991年）《欧洲生物化学杂志》201卷，283 - 287页]，通过在水溶液和甲醇溶液中结合使用核磁共振技术得以完全阐明。这种新型代谢产物被鉴定为3 - 甲基 - 1,2,3,4 - 四羟基丁烷 - 1,3 - 环双磷酸酯，并给出了最低能量构象。两个手性中心具有相对构型RS。
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