[(L)Ni(μ2-S)x{Fe(CO)3}x]加合物（x = 1或2）的形成：[NiFe]氢化酶活性位点的类似物
Formation of [(L)Ni(mu2-S)x{Fe(CO)3}x] adducts (x = 1 or 2): analogues of the active site of [NiFe] hydrogenase.
作者信息
Stenson Philip A, Marin-Becerra Armando, Wilson Claire, Blake Alexander J, McMaster Jonathan, Schröder Martin
机构信息
School of Chemistry, University of Nottingham, Nottingham, UK NG7 2RD.
出版信息
Chem Commun (Camb). 2006 Jan 21(3):317-9. doi: 10.1039/b509798c. Epub 2005 Nov 24.
DOI:10.1039/b509798c
PMID:16391746
Abstract
The binuclear [Ni(L)Fe(CO)3], , and trinuclear [Ni(L){Fe(CO)3}2], , complexes adopt unusual structural motifs whereby Fe(CO)3 units bind to [Ni(L)] via mu2-S bridging modes, C=N imine pi-bonds and potential Ni-Fe bonding interactions.
摘要
双核[Ni(L)Fe(CO)₃]和三核[Ni(L){Fe(CO)₃}₂]配合物呈现出不同寻常的结构模式，其中Fe(CO)₃单元通过μ₂-S桥连模式、C=N亚胺π键以及潜在的Ni-Fe键相互作用与[Ni(L)]结合。
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