Yan Xiao-Jun, Yang Da-Zhi
Department of Materials Engineering, Dalian University of Technology, Liaoning, Dalian, 116024, People's Republic of China.
J Biomed Mater Res A. 2006 Apr;77(1):97-102. doi: 10.1002/jbm.a.30378.
The purpose of this study was to investigate corrosion resistance of a laser spot-welded joint of NiTi alloy wires using potentiodynamic tests in Hank's solution at different PH values and the PH 7.4 NaCl solution for different Cl- concentrations. Scanning electron microscope observations were carried out before and after potentiodynamic tests. The composition of a laser spot-welded joint and base metal were characterized by using an electron probe microanalyzer. The results of potentiodynamic tests showed that corrosion resistance of a laser spot-welded joint of NiTi alloy wire was better than that of base metal, which exhibited a little higher breakdown potential and passive range, and a little lower passive current density. Corrosion resistances of a laser spot-welded joint and base metal decreased with increasing of the Cl- concentration and PH value. The improvement of corrosion resistance of the laser spot-welded joint was due to the decrease of the surface defects and the increase of the Ti/Ni ratio.
本研究的目的是通过在不同pH值的汉克斯溶液以及不同Cl-浓度的pH 7.4 NaCl溶液中进行动电位测试,研究镍钛合金丝激光点焊接头的耐腐蚀性。在动电位测试前后进行扫描电子显微镜观察。使用电子探针微分析仪对激光点焊接头和母材的成分进行表征。动电位测试结果表明,镍钛合金丝激光点焊接头的耐腐蚀性优于母材,其击穿电位和钝化范围略高,钝化电流密度略低。激光点焊接头和母材的耐腐蚀性随Cl-浓度和pH值的增加而降低。激光点焊接头耐腐蚀性的提高归因于表面缺陷的减少和Ti/Ni比的增加。