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聚合物易位:逆流的影响。

Polymer translocation: the effect of backflow.

作者信息

Ali I, Yeomans J M

机构信息

Department of Physics, College of Science, Sultan Qaboos University, P.O. Box 36, Al-Khod 123, Oman.

出版信息

J Chem Phys. 2005 Dec 15;123(23):234903. doi: 10.1063/1.2138702.

Abstract

We investigate the effect of backflow on the translocation dynamics of short, flexible polymer chains threading through a small hole in a wall. We find that hydrodynamic interactions between polymer beads play an important role in determining the translocation time distribution: as a monomer moves through the hole it sets up a flow field which transfers momentum to neighboring monomers, thus helping them to move in the same direction. Translocation times are calculated by using the velocity-Verlet algorithm to solve the equations of motion of a polymer which moves in a fluid described by the stochastic rotation algorithm, a particle-based Navier-Stokes solver.

摘要

我们研究了回流对短而柔性的聚合物链穿过壁上小孔的转移动力学的影响。我们发现聚合物珠之间的流体动力学相互作用在确定转位时间分布中起着重要作用:当一个单体穿过小孔时,它会建立一个流场,该流场将动量传递给相邻的单体,从而帮助它们沿相同方向移动。通过使用速度-维里算法求解聚合物在由随机旋转算法(一种基于粒子的纳维-斯托克斯求解器)描述的流体中运动的运动方程来计算转位时间。

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