Rotondo Archimede
Dipartimento di Chimica Inorganica, Chimica Analitica e Chimica Fisica, Universitá degli Studi di Messina, Via Salita Sperone 31, 98166 Vill. S. Agata, Messina, Italy.
Acta Crystallogr C. 2006 Jan;62(Pt 1):m19-21. doi: 10.1107/S0108270105040163. Epub 2005 Dec 24.
The crystal structure of the title compound, Pt(C6H7N)2(C20H16N4)2.C3H6O.0.5H2O, is composed of a bivalent square-planar platinum(II) complex, two PF6- counter-ions and solvent molecules. The di-2-pyridylquinoxaline ligands are known to confer an 'L shape' on square-planar platinum(II) complexes, which also display intercalating properties. The structural characterization reported here is a contribution to a wide-ranging study focused on structural and dynamical analyses of these substrates, which may provide better insight into their biological mechanisms and activities. The expected 'L-shaped' skeleton of the metallic complex combined with the antiparallel orientation of substituted pyridines (anti conformation) generates chiral objects, found in the solid state as a racemic mixture.