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近晶型液晶研究的当前主题。

Current topics in smectic liquid crystal research.

作者信息

Lagerwall Jan P F, Giesselmann Frank

机构信息

Institute of Physical Chemistry, University of Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, Germany.

出版信息

Chemphyschem. 2006 Jan 16;7(1):20-45. doi: 10.1002/cphc.200500472.

Abstract

Interest in the smectic liquid-crystalline state of matter received a substantial boost with the discovery by Meyer in the mid-1970s that a chiral smectic C (SmC*) phase exhibits a spontaneous electric polarization, and with the subsequent demonstration by Clark and Lagerwall of the surface-stabilized SmC* ferroelectric liquid crystal at the beginning of the 1980s. Since then, chiral smectic phases and their plethora of polar effects have dominated the research in this field, which today has reached a mature state where the first commercial microdisplay applications are now shipping in millions-per-year quantities. In this Review we discuss some of the topics of highest interest in current smectic liquid crystal research, and address application-relevant research (de Vries-type tilting transitions without defect generation and high-tilt antiferroelectric liquid crystals with perfect dark state) as well as more curiosity-driven research (the nature and origin of the chiral smectic C subphases and their intermediate frustrated states between ferro- and antiferroelectricity).

摘要

20世纪70年代中期迈耶发现手性近晶C(SmC*)相呈现出自发电极化,以及20世纪80年代初克拉克和拉格瓦尔证明了表面稳定的SmC*铁电液晶,这使得对近晶态液晶物质的研究兴趣得到了极大的推动。从那时起,手性近晶相及其众多的极化效应主导了该领域的研究,如今该领域已发展成熟,首批商业微显示器应用产品正以每年数百万的数量出货。在本综述中,我们讨论了当前近晶液晶研究中一些最受关注的主题,并探讨了与应用相关的研究(无缺陷产生的德弗里斯型倾斜转变和具有完美暗态的高倾斜反铁电液晶)以及更多出于好奇心驱动的研究(手性近晶C亚相的性质和起源及其在铁电和反铁电之间的中间受挫状态)。

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