Lin Dong-Qiang, Miao Zhi-Jun, Yao Shan-Jing
Department of Chemical and Biochemical Engineering, Zhejiang University, Hangzhou 310027, China.
J Chromatogr A. 2006 Feb 24;1107(1-2):265-72. doi: 10.1016/j.chroma.2005.11.049. Epub 2006 Jan 9.
For better understanding the influences of solid phase properties on the performance of the expanded bed, the expansion and hydrodynamic properties of cellulose-stainless steel powder composite matrix with a series of densities was investigated and analyzed in an expanded bed. Two kinds of matrix particle diameter fractions, the small one (60-125 microm) and the large (125-300 microm), were used in the present work. In general, the expansion factors decreased obviously with the increase of matrix density. A linear relation between the mean density of matrix and superficial velocity at expansion factor of 2.5 was found for same series of matrices. The Richardson-Zaki equation could correlate the bed expansion and operation fluid velocity for all matrices tested. The theoretical prediction of correlation parameters (the terminal settling velocity U(t) and expansion index n) was improved with the modification of equations in the literature. The residence time distributions were investigated to characterize the hydrodynamic property in expanded bed. Compared with three evaluation factors (the height equivalent of theoretical plate, Bo number and axial distribution coefficient D(ax)), the results indicated that D(ax) is the best parameter to analyze the bed stability of expanded bed under various operation conditions and matrix properties. In addition, it was found that fluid velocity is the most essential factor to influence the hydrodynamic properties in the bed. A linear relation between the D(ax) and superficial fluid velocity for all matrices tested was established.
为了更好地理解固相性质对膨胀床性能的影响,在膨胀床中对一系列密度的纤维素 - 不锈钢粉末复合基质的膨胀和流体动力学性质进行了研究与分析。本研究使用了两种基质粒径级分,小粒径级分(60 - 125微米)和大粒径级分(125 - 300微米)。总体而言,随着基质密度的增加,膨胀因子明显降低。对于同一系列的基质,发现在膨胀因子为2.5时,基质的平均密度与表观速度之间存在线性关系。Richardson - Zaki方程可以关联所有测试基质的床层膨胀和操作流体速度。通过修正文献中的方程,改进了关联参数(终端沉降速度U(t)和膨胀指数n)的理论预测。研究了停留时间分布以表征膨胀床中的流体动力学性质。与三个评估因子(理论塔板高度、Bo数和轴向分布系数D(ax))相比,结果表明D(ax)是分析不同操作条件和基质性质下膨胀床床层稳定性的最佳参数。此外,发现流体速度是影响床层流体动力学性质的最关键因素。建立了所有测试基质的D(ax)与表观流体速度之间的线性关系。