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2-氨基吡啶和2-氨基甲基吡啶的振动光谱与简正坐标分析

Vibrational spectra and normal co-ordinate analysis of 2-aminopyridine and 2-amino picoline.

作者信息

Jose Sujin P, Mohan S

机构信息

Annai Fathima College, Madurai 625706, India.

出版信息

Spectrochim Acta A Mol Biomol Spectrosc. 2006 May 1;64(1):240-5. doi: 10.1016/j.saa.2005.06.043. Epub 2006 Jan 9.

DOI:10.1016/j.saa.2005.06.043
PMID:16406840
Abstract

The Fourier transform infrared (FT-IR) and Raman (FT-R) spectra of 2-aminopyridine and 2-amino picoline were recorded and the observed frequencies were assigned to various modes of vibration in terms of fundamentals by assuming Cs point group symmetry. A normal co-ordinate analysis was also carried out for the proper assignment of the vibrational frequencies using simple valence force field. A complete vibrational analysis is presented here for the molecules and the results are briefly discussed.

摘要

记录了2-氨基吡啶和2-氨基甲基吡啶的傅里叶变换红外(FT-IR)光谱和拉曼(FT-R)光谱,并通过假设Cs点群对称性,将观测到的频率根据基频分配到各种振动模式。还使用简单价键力场进行了正常坐标分析,以正确分配振动频率。本文给出了这些分子的完整振动分析,并简要讨论了结果。

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