Crosa Giuseppe, Stefani Fabrizio, Bianchi Camilla, Fumagalli Alessandro
Department of Biotechnology and Molecular Sciences, Via Dunant 3, 20100 Varese Italy.
Environ Sci Pollut Res Int. 2006 Jan;13(1):37-42. doi: 10.1065/espr2006.01.007.
GOAL, SCOPE AND BACKGROUND: Amu Darya river, one of the main water resources of Uzbekistan, shows a relevant longitudinal enrichment of soluble contents which strongly limits the human uses of its waters. Because of the low natural run-off processes, salts and pollutants are mainly driven to the river by the return waters used for washing and irrigating the surrounding lands. The influence of return waters on stream quality is dramatically relevant in the lower reaches of the river where almost all the flowing waters have been previously used for the agriculture practises. To provide analytical evidence on the potential effects of return waters on the quality of the Amu Darya river, the paper reports and comments data on salinity and metals contents of the waters flowing in the artificial channel network of Bukhara and in the Amu Darya river, from Bukhara up to the dam forming the Tuyamuyn Hydro Complex (THC).
A total of 15 sampling sites were selected for the analytical survey: Two sites were located on the Amu Darya river downstream from the inflow of the return waters from Bukhara, two in the river entering in the THC, and three downstream from the dam forming the reservoir complex. The waters entering and leaving the Bukhara agricultural area were sampled in two main collectors, while the waters flowing in the channel system were sampled in six distinct collectors. The following parameters were considered in the survey: pH, Oxygen, Hardness, Salinity, Conductivity, P-PO4(3-), P tot, N tot, N-NO3(2-), N-NO2-, COD, Ca2+, Mg2+, Fe, Mn, Zn, Cr, Cu, Ni, Cd, Pb.
Salt concentrations below 1000 mg/l were measured in the Amu Darya waters upstream to Bukhara. In the drainage system, salinity exceeds the palatability limit and reaches the maximum peak of 3200 mg/l in the outflow collector. Due to dilution effects, salinity returns to lower values (400-700 mg/l) along the Amu Darya river downstream from Bukhara; calcium and magnesium resulted the major constituents of the overall salinity. No serious metal contaminations were detected in the waters entering and leaving the examined channel system. Differently, the Amu Darya waters upstream to the THC showed a relevant metal contamination, with Cr, Ni, Fe concentrations exceeding the limits for human consumption. In the downstream sites, located in the Tuyamuyn Hydro Complex and in the Amu Darya river flowing out from this reservoir, excluding Fe, all the examined metals showed lover concentrations and values below the normative limits.
The direct human consumption of the lower Amu Darya waters is strongly limited by salinity and by metal contamination. Although the salinity of the return waters from the Bukhara drainage system results in above normal limits, no corresponding increases were measured in the Amu Darya river downstream from the return water inflow at the time of the survey. As for the metal contamination of the Amu Darya river, the survey revealed the presence of relevant sources of metal contamination downstream from Bukhara external to the agricultural drainage system. This contamination resulted in reduced sedimentation processes taking place in the limnetic zones of the Amu Darya river upstream to the dam forming the Tuyamuyn Hydro Complex.
To fully understand the longitudinal increase of Amu Darya salinity, an evaluation of the cumulative effects of the loads from the main agricultural areas is required, also by using mass-balance models. As for the metals, an investigation should be addressed to identify the anthropogenic sources of contaminations present in the lower Amu Darya region and the metal loads should be diverted.
目标、范围与背景:阿姆河是乌兹别克斯坦的主要水资源之一,其可溶性成分在纵向上有显著富集,这严重限制了河水的人类利用。由于自然径流过程较弱,盐分和污染物主要通过用于冲洗和灌溉周边土地的回流水进入河流。回流水对河流水质的影响在河流下游极为显著,因为几乎所有的流水此前都已用于农业生产。为了提供回流水对阿姆河水质潜在影响的分析证据,本文报告并评论了布哈拉人工渠道网络以及从布哈拉到形成图亚穆恩水利枢纽(THC)大坝之间的阿姆河水中盐度和金属含量的数据。
共选择了15个采样点进行分析调查:两个位于阿姆河布哈拉回流水流入点下游,两个在流入THC的河段,三个在形成水库综合体的大坝下游。进入和离开布哈拉农业区的水在两个主要集水区采样,而在渠道系统中流动的水在六个不同集水区采样。调查中考虑了以下参数:pH值、氧气、硬度、盐度、电导率、P - PO4(3-)、总磷、总氮、N - NO3(2-)、N - NO2-、化学需氧量、Ca2+、Mg2+、Fe、Mn、Zn、Cr、Cu、Ni、Cd、Pb。
在布哈拉上游的阿姆河水中测得盐浓度低于1000毫克/升。在排水系统中,盐度超过适口性极限,在流出集水区达到3200毫克/升的最高峰值。由于稀释作用,布哈拉下游的阿姆河沿线盐度恢复到较低值(400 - 700毫克/升);钙和镁是总盐度的主要成分。在所检查的渠道系统进出水中未检测到严重的金属污染。不同的是,THC上游的阿姆河水中存在显著的金属污染,Cr、Ni、Fe浓度超过人类消费限值。在下游站点,位于图亚穆恩水利枢纽以及从此水库流出的阿姆河段,除Fe外,所有检测的金属浓度较低且值低于规范限值。
阿姆河下游水的直接人类消费受到盐度和金属污染的严重限制。尽管布哈拉排水系统的回流水盐度超出正常限值,但在调查时,回流水流入下游的阿姆河水中未测得相应增加。至于阿姆河的金属污染,调查显示在布哈拉外部农业排水系统下游存在显著的金属污染源。这种污染导致在形成图亚穆恩水利枢纽大坝上游的阿姆河湖泊区发生的沉积过程减少。
为了全面了解阿姆河盐度的纵向增加,需要通过使用质量平衡模型评估主要农业区负荷的累积影响。至于金属,应进行调查以确定阿姆河下游地区存在的人为污染源,并应转移金属负荷。