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[红壤中倍硫磷与毒虫畏复合污染物的降解调控]

[Degradation regulation of fenthion and chlorfenvinfos combined pollutants in red soil].

作者信息

Wang Li-gang, Jiang Xin, Mao Ying-ming, Su Yi-rong, Wu Jing-shui

机构信息

Institute of Subtropical Agriculture, Chinese Academy of Sciences, Changsha 410125, China.

出版信息

Huan Jing Ke Xue. 2005 Nov;26(6):159-63.

Abstract

The degrading regulations of combined pollutants of chlorfenvinfos and fenthion in red soil were studied, in which soil incubation, gas chromatography with nitrogen-phosphorus detection for analysis are utilized. The main conclusions drawn are as follows: under combined pollution condition, the degrading amount of fenthion was significantly higher than that of fenthion alone in soil; under saturated soil humidity, the degrading amount of fenthion was less changed, while that of chlorfenvinfos was increased by 33.3% - 1250%. Soil drought made degradation amount of fenthion decreased a little, while made chlorfenvinfos increased significantly prior to the 21st day after addition of pesticide; nitrogen fertilizer application stimulated both fenthion and chlorfenvinfos degraded; the chemical degrading amount of fenthion in soil with organic matter eliminated was decreased by 22.4% - 30.8%, while that of chlorfenvinfos was increased 42.1% - 2370% at the earlier stage, and was decreased 11% - 17.3% at the later stage. Therefore, there are differences of degrading regulation between single pesticide pollutant and combined pesticide pollutants in soil, and the degradation of organophosphorus pesticides in combined pollutants are influenced with each other.

摘要

研究了毒死蜱与倍硫磷复合污染物在红壤中的降解规律,采用土壤培养法,利用氮磷检测器气相色谱法进行分析。得出的主要结论如下:在复合污染条件下,土壤中倍硫磷的降解量显著高于单独施加倍硫磷时的降解量;在土壤湿度饱和时,倍硫磷的降解量变化较小,而毒死蜱的降解量增加了33.3% - 1250%。土壤干旱使倍硫磷的降解量略有下降,而在施药后第21天前毒死蜱的降解量显著增加;施用氮肥促进了倍硫磷和毒死蜱的降解;去除有机质的土壤中倍硫磷的化学降解量减少了22.4% - 30.8%,而毒死蜱的化学降解量在前期增加了42.1% - 2370%,后期减少了11% - 17.3%。因此,土壤中单一农药污染物与复合农药污染物的降解规律存在差异,复合污染物中有机磷农药的降解相互影响。

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