亚铁离子与氰根离子反应的进一步研究：顺式和反式[FeII,III(CN)4L2]n-配合物的合成与表征
Further study of the reaction of Fe2+ with CN-: synthesis and characterization of cis and trans [FeII,III(CN)4L2]n- complexes.
作者信息
Chiarella Gina M, Melgarejo Doris Y, Koch Stephen A
机构信息
Department of Chemistry, State University of New York at Stony Brook, Stony Brook, New York 11794-3400, USA.
出版信息
J Am Chem Soc. 2006 Feb 8;128(5):1416-7. doi: 10.1021/ja0571951.
Abstract
The reaction of Fe2+ with CN-, which was first performed in 1704, has been used to synthesize a new series of basic [FeII,III(CN)4L2]n- complexes, where L is a monodentate ligand. trans-Na2[FeII(CN)4(DMSO)2] and cis-[NEt4]2[FeII(CN)4(pyridine)2] are synthesized by the direct reaction of FeCl2 with 4 equiv of CN- in DMSO or pyridine. Air oxidation of the latter compound gives cis-[NEt4][FeIII(CN)4(pyridine)2]. The non-cyanide ligands in these complexes undergo facile ligand exchange reactions with solvent. Reaction of cis-[NEt4]2[FeII(CN)4(pyridine)2] with CO at room temperature gives trans-[NEt4]2[FeII(CN)4(pyridine)(CO)].
摘要
Fe2+与CN-的反应最早于1704年进行，已被用于合成一系列新的碱性[FeII,III(CN)4L2]n-配合物，其中L是单齿配体。通过FeCl2与4当量的CN-在二甲基亚砜（DMSO）或吡啶中直接反应合成反式-Na2[FeII(CN)4(DMSO)2]和顺式-[NEt4]2[FeII(CN)4(pyridine)2]。后一种化合物的空气氧化得到顺式-[NEt4][FeIII(CN)4(pyridine)2]。这些配合物中的非氰化物配体与溶剂容易发生配体交换反应。顺式-[NEt4]2[FeII(CN)4(pyridine)2]在室温下与CO反应得到反式-[NEt4]2[FeII(CN)4(pyridine)(CO)]。
相似文献
1
Further study of the reaction of Fe2+ with CN-: synthesis and characterization of cis and trans [FeII,III(CN)4L2]n- complexes.亚铁离子与氰根离子反应的进一步研究：顺式和反式[FeII,III(CN)4L2]n-配合物的合成与表征
J Am Chem Soc. 2006 Feb 8;128(5):1416-7. doi: 10.1021/ja0571951.
2
Six-coordinate and five-coordinate Fe(II)(CN)(2)(CO)(x) thiolate complexes (x = 1, 2): synthetic advances for iron sites of [NiFe] hydrogenases.六配位和五配位的Fe(II)(CN)(2)(CO)(x)硫醇盐配合物（x = 1, 2）：[NiFe]氢化酶铁位点的合成进展
J Am Chem Soc. 2002 Feb 27;124(8):1680-8. doi: 10.1021/ja011504f.
3
fac-[Fe(II)(CN)(3)(CO)(3)](-) and cis-[Fe(II)(CN)(4)(CO)(2)](2)(-): new members of the class of [Fe(II)(CN)(x)(CO)(y)] compounds.
Inorg Chem. 2002 Jan 28;41(2):158-60. doi: 10.1021/ic015604y.
4
Electronic structure of mononuclear bis(1,2-diaryl-1,2-ethylenedithiolato)iron complexes containing a fifth cyanide or phosphite ligand: a combined experimental and computational study.含第五个氰化物或亚磷酸酯配体的单核双（1,2 - 二芳基 - 1,2 - 乙二硫醇根）铁配合物的电子结构：实验与计算相结合的研究
Inorg Chem. 2006 Sep 18;45(19):7877-90. doi: 10.1021/ic061171t.
5
Preparative and structural studies on iron(II)-thiolate cyanocarbonyls: relevance to the [NiFe]/[Fe]-hydrogenases.铁（II）硫醇盐氰基羰基化合物的制备与结构研究：与[NiFe]/[Fe]氢化酶的相关性
Dalton Trans. 2004 Jan 7(1):137-43. doi: 10.1039/b311059a. Epub 2003 Nov 24.
6
Versatile reactivity of a solvent-coordinated diiron(II) compound: synthesis and dioxygen reactivity of a mixed-valent Fe(II)Fe(III) species.溶剂配位二铁(II)化合物的多功能反应性：混合价态 Fe(II)Fe(III)物种的合成和氧气反应性。
Inorg Chem. 2014 Jan 6;53(1):167-81. doi: 10.1021/ic4019585. Epub 2013 Dec 20.
7
Fe(II) mononuclear complexes with a new aminopyridyl ligand bearing a pivaloylamido arm. Preparation and spectroscopic characterizations of a Fe(III)-hydroperoxo complex with oxygen and nitrogen donors.具有新的带有新戊酰氨基臂的氨基吡啶配体的亚铁单核配合物。含氮氧供体的铁（III）-氢过氧配合物的制备与光谱表征。
Inorg Chem. 2007 Mar 5;46(5):1709-17. doi: 10.1021/ic0623415. Epub 2007 Feb 8.
8
Two-dimensional materials based on trans-[FeII(CN)4(CO)2]2- building blocks; first structural evidence for a hydrated metal carbonyl ligation.
Chem Commun (Camb). 2002 Aug 21(16):1724-5. doi: 10.1039/b200337f.
9
Diferrous cyanides as models for the Fe-only hydrogenases.二价铁氰化物作为仅含铁氢化酶的模型。
J Am Chem Soc. 2005 Aug 10;127(31):11010-8. doi: 10.1021/ja051584d.
10
Synthetic and structural studies on [Fe2(SR)2(CN)x(CO)6-x](x-) as active site models for Fe-only hydrogenases.作为仅含铁氢化酶活性位点模型的[Fe2(SR)2(CN)x(CO)6-x](x-)的合成与结构研究
J Am Chem Soc. 2001 Dec 19;123(50):12518-27. doi: 10.1021/ja016071v.
引用本文的文献
1
Electrochemical oxidation of ferricyanide.电化学氧化铁氰化物。
Sci Rep. 2021 Nov 29;11(1):23058. doi: 10.1038/s41598-021-02355-3.
本文引用的文献
1
Preparative and structural studies on iron(II)-thiolate cyanocarbonyls: relevance to the [NiFe]/[Fe]-hydrogenases.铁（II）硫醇盐氰基羰基化合物的制备与结构研究：与[NiFe]/[Fe]氢化酶的相关性
Dalton Trans. 2004 Jan 7(1):137-43. doi: 10.1039/b311059a. Epub 2003 Nov 24.
2
Synthesis and reactivity of Ru-, Os-, Rh-, and Ir-halide-sulfoxide complexes.
Chem Rev. 2004 Sep;104(9):4203-42. doi: 10.1021/cr0307291.
3
High-nuclearity metal-cyanide clusters: synthesis, magnetic properties, and inclusion behavior of open-cage species incorporating [(tach)M(CN)3] (M = Cr, Fe, Co) complexes.高核金属氰化物簇合物：包含[(tach)M(CN)₃]（M = Cr、Fe、Co）配合物的笼状开放物种的合成、磁性及包合行为
Inorg Chem. 2003 Mar 10;42(5):1403-19. doi: 10.1021/ic026065f.
4
Two-dimensional materials based on trans-[FeII(CN)4(CO)2]2- building blocks; first structural evidence for a hydrated metal carbonyl ligation.
Chem Commun (Camb). 2002 Aug 21(16):1724-5. doi: 10.1039/b200337f.
5
Preparative and structural studies on the carbonyl cyanides of iron, manganese, and ruthenium: fundamentals relevant to the hydrogenases.铁、锰和钌的羰基氰化物的制备及结构研究：与氢化酶相关的基础研究
Inorg Chem. 2002 Mar 25;41(6):1670-8. doi: 10.1021/ic011030l.
6
Six-coordinate and five-coordinate Fe(II)(CN)(2)(CO)(x) thiolate complexes (x = 1, 2): synthetic advances for iron sites of [NiFe] hydrogenases.六配位和五配位的Fe(II)(CN)(2)(CO)(x)硫醇盐配合物（x = 1, 2）：[NiFe]氢化酶铁位点的合成进展
J Am Chem Soc. 2002 Feb 27;124(8):1680-8. doi: 10.1021/ja011504f.
7
fac-[Fe(II)(CN)(3)(CO)(3)](-) and cis-[Fe(II)(CN)(4)(CO)(2)](2)(-): new members of the class of [Fe(II)(CN)(x)(CO)(y)] compounds.
Inorg Chem. 2002 Jan 28;41(2):158-60. doi: 10.1021/ic015604y.
8
Chemistry of [Fe(II)(CN)(5)(CO)](3-) new observations for a 19th century compound.
J Am Chem Soc. 2001 Dec 5;123(48):12109-10. doi: 10.1021/ja016434r.
9
trans-.
Angew Chem Int Ed Engl. 2001 Jul 16;40(14):2629-2631.
10
The influence of cyanide on the carbonylation of iron(II): synthesis of Fe-Sr-Cn-Co centers related to the hydrogenase active sites.
J Am Chem Soc. 2001 Jul 18;123(28):6933-4. doi: 10.1021/ja015948n.
Zotero 插件