电化学氧化铁氰化物。
Electrochemical oxidation of ferricyanide.
机构信息
Molecular Biomimetics, Department of Chemistry - Ångström Laboratory, Uppsala University, Box 523, 75120, Uppsala, Sweden.
出版信息
Sci Rep. 2021 Nov 29;11(1):23058. doi: 10.1038/s41598-021-02355-3.
We report the electrochemical oxidation of ferricyanide, [Fe(CN)] and characterised the oxidation product by in-situ FTIR and XAS spectroelectrochemistry methods. Oxidation of [Fe(CN)] is proposed to proceed via a tentative Fe(IV) intermediate that undergoes reduction elimination to give cis-[Fe(CN)(CHCN)] as stable product in acetonitrile. Speciation of the oxidation product by DFT calculations is underpinned by good agreement to experimental data.
我们报告了铁氰化物[Fe(CN)]的电化学氧化，并通过原位傅里叶变换红外光谱（FTIR）和 X 射线吸收光谱（XAS）光谱电化学方法对氧化产物进行了表征。[Fe(CN)]的氧化被认为是通过一个暂定的 Fe(IV)中间体进行的，该中间体经历还原消除，在乙腈中生成稳定产物顺式-[Fe(CN)(CHCN)]。通过密度泛函理论（DFT）计算对氧化产物的形态进行了研究，实验数据与计算结果吻合较好。
Zotero 插件