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具有生物除磷功能的污水处理厂中的磷回收

Phosphorus recycling in sewage treatment plants with biological phosphorus removal.

作者信息

Heinzmann B

机构信息

Berliner Wasserbetriebe, Cicerostrasse 24, D-10709 Berlin, Germany.

出版信息

Water Sci Technol. 2005;52(10-11):543-8.

Abstract

In this paper, phosphorus balances are calculated for the wastewater purification and sludge treatment stages for wastewater treatment plants (WWTPs) applying Enhanced Biological Phosphorus Removal (EBPR). The possible P-recovery potential is then estimated and evaluated regarding different locations along the process of wastewater purification and sludge treatment, taking the different phosphorus bonding forms into account. Caused by the more favourable bonding forms in the excess sludge as well as possibly also in the sludge ash a recovery of the phosphorus seems especially favoured for WWTPs with EBPR. The processes available for a P recycling are named, and special regard is given to the Phostrip-process, which is a possible recycling process already tested in practice. Further R&D demand consists in basic research regarding disintegration, fermentation or acidic total digestion of excess sludge followed by phosphorus precipitation including separation of the precipitates, MAP-precipitation and separation from digested sludge and on the ability to extract phosphorus and heavy metals from sewage sludge ash. These investigations are a precondition to enable purposeful process developments. At the present state the cost of recycled phosphorus earned from wastewater, sludge and ash, respectively, are a multiple higher than the costs for raw phosphate taking into account the suitable processes. Thus, up to now no phosphorus recycling with a defrayal of costs is possible. The future importance of phosphorus recycling will depend on the market price for raw phosphate, the recycling costs and, furthermore, on the general political framework.

摘要

本文针对采用强化生物除磷(EBPR)的污水处理厂(WWTPs)的废水净化和污泥处理阶段,计算了磷平衡。然后,考虑到不同的磷结合形式,针对废水净化和污泥处理过程中不同位置,估算并评估了可能的磷回收潜力。由于剩余污泥以及可能还有污泥灰中更有利的结合形式,对于采用EBPR的污水处理厂而言,磷回收似乎特别有利。列举了可用于磷回收的工艺,并特别关注了Phostrip工艺,该工艺是一种已在实践中测试过的可能的回收工艺。进一步的研发需求包括对剩余污泥的分解、发酵或酸性全消化进行基础研究,随后进行磷沉淀,包括沉淀物的分离、鸟粪石沉淀以及从消化污泥中分离,以及从污水污泥灰中提取磷和重金属的能力。这些研究是实现有针对性的工艺开发的前提条件。在当前状态下,考虑到合适的工艺,分别从废水、污泥和灰中回收磷的成本比原生磷酸盐的成本高出数倍。因此,到目前为止,无法实现成本可收回的磷回收。磷回收的未来重要性将取决于原生磷酸盐的市场价格、回收成本,此外还取决于总体政治框架。

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