Chen Chun-yun, Wang Peng, Zhuang Yuan-yi
School of Municipal and Environmental Engineering, Harbin Institute of Technology, Harbin 150090, China.
J Environ Sci (China). 2005;17(6):1018-21.
Sewage sludge was used to develop an effective carbon adsorbent. This adsorbent was employed for the removal of azo dye such as Direct Dark Brown M and Acid Mordant Brown RH. The adsorption of dyes on this adsorbent was studied as a function of contact time, concentration, pH and temperature by batch method. The equilibrium adsorption capacity of a carbonaceous adsorbent prepared from city wastewater treatment plant was 502, and 329.7 mg/g of Direct Dark Brown M and Acid Mordant Brown RH, respectively. The experimental data were analyzed by the Langmuir and Freundlich models of adsorption. Equilibrium data fitted well with the Langmuir model. The rates of adsorption were found to conform to the Lagergren second-order kinetics with good correlation. The equilibrium adsorption capacity of the carbonaceous adsorbents was determined with the Langmuir equation as well as the Lagergren second-order rate equation. The most ideal pH for adsorption of two dyes onto adsorbents was found to be 3 and below. The results indicate that the carbonaceous adsorbents could be employed as a low cost adsorbent in the removal of dyes from wastewater.
利用污水污泥制备了一种高效的碳吸附剂。该吸附剂用于去除偶氮染料,如直接深棕M和酸性媒介棕RH。采用分批法研究了染料在该吸附剂上的吸附作用与接触时间、浓度、pH值和温度的关系。由城市污水处理厂制备的碳质吸附剂对直接深棕M和酸性媒介棕RH的平衡吸附容量分别为502和329.7 mg/g。采用Langmuir和Freundlich吸附模型对实验数据进行了分析。平衡数据与Langmuir模型拟合良好。吸附速率符合Lagergren二级动力学,相关性良好。用Langmuir方程和Lagergren二级速率方程确定了碳质吸附剂的平衡吸附容量。发现两种染料在吸附剂上吸附的最理想pH值为3及以下。结果表明,碳质吸附剂可作为一种低成本吸附剂用于去除废水中的染料。