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在锶特异性离子交换柱上分离后,通过液体闪烁光谱法测定鹿骨中的锶-90。

Determination of strontium-90 in deer bones by liquid scintillation spectrometry after separation on Sr-specific ion exchange columns.

作者信息

Landstetter Claudia, Wallner Gabriele

机构信息

Institute for Inorganic Chemistry, University of Vienna, Waehringerstrasse 42, A-1090 Vienna, Austria.

出版信息

J Environ Radioact. 2006;87(3):315-24. doi: 10.1016/j.jenvrad.2005.12.008. Epub 2006 Feb 20.

Abstract

The activity concentration of (90)Sr was determined in several deer bones from Austria. Strontium specific ion exchange columns with 4',4''(5'')-di-t-butylcyclohexane-18-crown-6 from Eichrom Industries, Inc. were used for separation. The yield of the chemical procedure was quantified with AAS. Directly after column separation, the solution containing (90)Sr was mixed with the scintillation cocktail HiSafe III and measured by liquid scintillation counting. Prevention of (210)Pb contamination and reusability of the separation columns was investigated as well as the activity distribution within the bones. Results were compared with pre-Chernobyl measurements in Austria; a correlation between activity concentration of (90)Sr and site altitude was found.

摘要

测定了来自奥地利的几块鹿骨中(90)Sr的活度浓度。使用了Eichrom Industries, Inc.生产的带有4',4''(5'')-二叔丁基环己烷-18-冠-6的锶特异性离子交换柱进行分离。化学程序的产率用原子吸收光谱法进行定量。柱分离后,立即将含有(90)Sr的溶液与闪烁鸡尾酒HiSafe III混合,并通过液体闪烁计数法进行测量。研究了(210)Pb污染的预防和分离柱的可重复使用性以及骨骼内的活度分布。将结果与奥地利切尔诺贝利事故前的测量结果进行了比较;发现了(90)Sr活度浓度与地点海拔之间的相关性。

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