一种二铋烷R2Bi - BiR2[R = 2,6 - (Me2NCH2)2C6H3]的异构体以及与氧气的异常反应：生成[R2Bi]2(O2)和R'R''Bi[R' = 2 - (Me2NCH2)-6 - {Me2N(O)CH2}C6H3；R'' = 2 - (Me2NCH2)-6 - {O(O)C}C6H3] 。
Isomers of a dibismuthane, R2Bi-BiR2 [R = 2,6-(Me2NCH2)2C6H3], and unusual reactions with oxygen: formation of [R2Bi]2(O2) and R'R' 'Bi [R' = 2-(Me2NCH2)-6-{Me2N(O)CH2}C6H3; R' ' = 2-(Me2NCH2)-6-{O(O)C}C6H3].
作者信息
Balazs Lucia, Breunig Hans J, Lork Enno, Soran Albert, Silvestru Cristian
机构信息
Universität Bremen, Fachbereich 2, D-28334 Bremen, Germany.
出版信息
Inorg Chem. 2006 Mar 6;45(5):2341-6. doi: 10.1021/ic052160n.
R2Bi-BiR2 [1; R = 2,6-(Me2NCH2)2C6H3], a dibismuthane that exists in different forms in the crystalline state, reacts in air with the formation of the peroxide [R(2)Bi]2(O2) (2) and partial oxidation of the pendant (dimethylamino)methyl groups, yielding the mononuclear bismuth complex R'R' 'Bi (3) [R' = 2-(Me2NCH2)-6-{Me2N(O)CH2}C6H3; R' ' = 2-(Me2NCH2)-6-{O(O)C}C6H3].
R2Bi-BiR2 [1；R = 2,6-(二甲基氨基甲基)2苯], 一种在晶体状态下以不同形式存在的二铋烷，在空气中反应生成过氧化物[R(2)Bi]2(O2) (2)，且其侧链（二甲基氨基）甲基发生部分氧化，生成单核铋配合物R'R''Bi (3) [R' = 2-(二甲基氨基甲基)-6-{二甲基氨基（氧）甲基}苯；R'' = 2-(二甲基氨基甲基)-6-{氧（氧代）羰基}苯] 。
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