Notestein Justin M, Katz Alexander
Department of Chemical Engineering, University of California at Berkeley, Berkeley California 94720-1462, USA.
Chemistry. 2006 May 15;12(15):3954-65. doi: 10.1002/chem.200501152.
Active-site/surface cooperativity can enhance heterogeneous organic and organometallic catalysis. We review the powerful role of the solid surface in this context for generating local acidity and, as an inner-sphere ligand, for stabilizing immobilized supramolecular assemblies and unsaturated organometallic complexes that are often unstable in solution.
活性位点/表面协同作用可增强多相有机催化和有机金属催化。我们综述了在此背景下固体表面在产生局部酸性方面的重要作用，以及作为内球配体在稳定固定化超分子组装体和不饱和有机金属配合物方面的重要作用，这些组装体和配合物在溶液中通常不稳定。
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