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加速碳化处理城市固体废弃物焚烧底灰

Accelerated carbonation for treatment of MSWI bottom ash.

作者信息

Arickx S, Van Gerven T, Vandecasteele C

机构信息

Department of Chemical Engineering, Katholieke Universiteit Leuven, W. de Croylaan 46, B-3001 Leuven, Belgium.

出版信息

J Hazard Mater. 2006 Sep 1;137(1):235-43. doi: 10.1016/j.jhazmat.2006.01.059. Epub 2006 Mar 15.

Abstract

Leaching of heavy metals from MSWI bottom ash exceeds some of the Flemish limit values for recycling the material as granular construction application. In particular, leaching of Cu, Zn and Pb often exceeds the limit value, with Cu being the most critical. In order to recycle bottom ash, treatment is therefore required. The bottom ash studied was divided on-site into four fractions using a large-scale wet sieving installation: a sludge fraction (Ø 0-0.1mm), a sand fraction (Ø 0.1-2mm) and two gravel fractions (Ø 2-6 and 6-50mm). The two gravel fractions complied with the limit values after 3 months of natural ageing. The sand and sludge fraction did not reach the limit value for Cu. Four weeks of accelerated carbonation resulted in an important decrease of Cu leaching from these two fractions, although the limit value is still exceeded. In view of applying carbonation as one of the treatment methods in an integrated industrial application, two tests were additionally performed. The use of stack gas as carbonating medium was verified by setting up an accelerated carbonation experiment at the incineration plant. Also, the depth of carbonation was measured in a 10 cm thick sample of the sand fraction after different periods of treatment. After 3 months of natural ageing only the upper 4 cm underwent a significant carbonation, while after one week of accelerated carbonation the total sample was carbonated. A model was developed to predict these experimental results.

摘要

从城市固体废弃物焚烧底灰中浸出的重金属超过了弗拉芒地区将该材料作为颗粒状建筑材料回收利用的一些限值。特别是铜、锌和铅的浸出常常超过限值,其中铜最为关键。因此,为了回收底灰,需要进行处理。所研究的底灰在现场使用大型湿式筛分装置分为四个部分:一个污泥部分(粒径0 - 0.1毫米)、一个沙子部分(粒径0.1 - 2毫米)和两个砾石部分(粒径2 - 6毫米和6 - 50毫米)。经过3个月的自然老化后,两个砾石部分符合限值。沙子和污泥部分的铜浸出未达到限值。四周的加速碳酸化导致这两个部分的铜浸出显著减少,尽管仍超过限值。鉴于将碳酸化作为综合工业应用中的一种处理方法,还额外进行了两项试验。通过在焚烧厂进行加速碳酸化实验,验证了使用烟道气作为碳酸化介质。此外,在不同处理时间段后,对10厘米厚的沙子部分样品测量了碳酸化深度。经过3个月的自然老化后,只有上部4厘米经历了显著的碳酸化,而经过一周的加速碳酸化后,整个样品都被碳酸化了。开发了一个模型来预测这些实验结果。

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