Stuart Douglas A, Biggs Kevin B, Van Duyne Richard P
Department of Chemistry, Northwestern University, 2145 Sheridan Rd Evanston, IL 60208-3113, USA.
Analyst. 2006 Apr;131(4):568-72. doi: 10.1039/b513326b. Epub 2006 Feb 21.
The detection and identification of chemical warfare agents is an important analytical goal. Herein, it is demonstrated that 2-chloroethyl ethyl sulfide (half-mustard, CEES) can be successfully analysed using surface-enhanced Raman spectroscopy (SERS). A critical component in this detection system is the fabrication of a robust, yet highly enhancing, sensor surface. Recent advances in substrate fabrication and in the fundamental understanding of the SERS phenomenon enable the development of improved substrates for practical SERS applications.
化学战剂的检测与识别是一个重要的分析目标。在此,已证明使用表面增强拉曼光谱(SERS)能够成功分析2-氯乙基乙基硫醚(半芥子气,CEES)。该检测系统中的一个关键组件是制造一种坚固但增强效果极佳的传感器表面。基底制造以及对SERS现象基本理解方面的最新进展使得能够开发出用于实际SERS应用的改进基底。