席夫碱低聚吡咯大环中银（I）阳离子的正向同促变构结合
Positive homotropic allosteric binding of silver(I) cations in a Schiff base oligopyrrolic macrocycle.
作者信息
Sessler Jonathan L, Tomat Elisa, Lynch Vincent M
机构信息
Department of Chemistry and Biochemistry, The University of Texas at Austin, 78712-0165, USA.
出版信息
J Am Chem Soc. 2006 Apr 5;128(13):4184-5. doi: 10.1021/ja0582004.
PMID:16568966
Abstract
The binuclear silver(I) complex of a Schiff base oligopyrrolic macrocycle was prepared in high yield and fully characterized. UV-visible absorption and 1H NMR spectroscopic analyses reveal that coordination of Ag(I) cations is subject to a strong positive homotropic allosteric effect.
摘要
以高产率制备了一种席夫碱低聚吡咯大环的双核银（I）配合物，并对其进行了全面表征。紫外可见吸收光谱和1H NMR光谱分析表明，Ag（I）阳离子的配位受到强烈的正同配别构效应的影响。
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