作为用于金属介导化学基础气相研究的完整化学实验室的三维四极杆离子阱质谱仪。
The 3D quadrupole ion trap mass spectrometer as a complete chemical laboratory for fundamental gas-phase studies of metal mediated chemistry.
作者信息
O'Hair Richard A J
机构信息
School of Chemistry, University of Melbourne, Melbourne, Victoria 3010, Australia.
出版信息
Chem Commun (Camb). 2006 Apr 14(14):1469-81. doi: 10.1039/b516348j. Epub 2006 Jan 30.
DOI:10.1039/b516348j
PMID:16575433
Abstract
Electrospray ionization provides a "treasure trove" of metal containing ions whose fundamental reactivity can be studied via collision induced dissociation and ion-molecule reactions using the multistage mass spectrometry capabilities of the quadrupole ion trap mass spectrometer. Examples of metal mediated chemistry relevant to catalysis, C-C bond coupling, bioinorganic and supramolecular chemistry are highlighted.
摘要
电喷雾电离提供了一个包含金属离子的“宝库”，其基本反应活性可通过使用四极杆离子阱质谱仪的多级质谱功能，经由碰撞诱导解离和离子-分子反应来进行研究。文中突出了与催化、碳-碳键偶联、生物无机化学和超分子化学相关的金属介导化学的实例。
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