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在自旋交换相互作用的热滞现象中，配位不饱和d9金属中心的光致相变。

Photoinduced phase transition of coordinationally unsaturated d9 metal centers within the thermal hysteresis of the spin exchange interaction.

作者信息

Naumov Pance, Sakurai Kenji, Asaka Toru, Belik Alexei A, Adachi Shin-ichi, Takahashi Junichi, Koshihara Shin-ya

机构信息

ICYS, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan.

出版信息

Chem Commun (Camb). 2006 Apr 14(14):1491-3. doi: 10.1039/b516513j. Epub 2006 Feb 22.

DOI:10.1039/b516513j
PMID:16575437
Abstract

Diffraction evidence is presented that the structure of one-dimensional arrays of strained, coordinationally unsaturated d9 pseudo-Jahn-Teller centers is affected by excitation of the LMCT bands within the hysteresis region of the low-temperature ferromagnetic-to-antiferromagnetic phase transition.

摘要

有衍射证据表明，在低温铁磁到反铁磁相变的磁滞区内，应变的、配位不饱和的d9类 Jahn-Teller 中心的一维阵列结构会受到配体到金属电荷转移（LMCT）能带激发的影响。

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