Ginting Daniel, Mamo Martha
Department of Agronomy and Horticulture, University of Nebraska, Lincoln, NE 68583, USA.
J Environ Qual. 2006 Apr 3;35(3):815-23. doi: 10.2134/jeq2005.0219. Print 2006 May-Jun.
Differences in particle size distribution between runoff standards and unknown samples affect the accuracy of estimation of total suspended solids (TSS) concentration using the nephelometric turbidity (NTU) method. The objective was to quantify the effects of a sucrose solution as suspending medium and contrasting particle size distribution on nephelometric turbidity and accuracy of TSS estimation. Nineteen benchmark soils varying in texture and color were divided into particle size distribution of <250 and <2000 microm. Soils from these two aggregate classes were then made into suspension ranging from 0.2 to 15 g L-1 using distilled deionized water. Runoff suspensions ranging from 0.2 to 21 g L-1 were also collected from different watersheds. Turbidity of soil and runoff suspensions was measured in sucrose solution and in distilled deionized water. The sucrose solution density ranged from 1.10 to 1.30 kg L-1. Increasing sucrose solution density decreased turbidity. The TSS concentration was most sensitive to changes in turbidity with the 1.30 kg L-1 sucrose solution. Using the 1.30 kg L-1 sucrose solution, particle size bias and error of TSS estimates were decreased by at least 20% compared to distilled deionized water. Reduction in refraction index differences between the suspended particles and sucrose solution combined with reduced particle settling and reduced Brownian motion resulted in dampening the effects of particle size distribution. We propose a sucrose solution of 1.30 kg L-1 as a better suspending medium to dampen the effect of particle size distribution and thus improve suspension TSS concentration estimation.
径流标准样品与未知样品之间的粒径分布差异,会影响使用浊度法(NTU)估算总悬浮固体(TSS)浓度的准确性。本研究的目的是量化蔗糖溶液作为悬浮介质以及对比粒径分布对浊度法和TSS估算准确性的影响。选取了19种质地和颜色各异的基准土壤,将其分为粒径小于250微米和小于2000微米的粒径分布类别。然后,使用蒸馏去离子水将这两类团聚体的土壤制成浓度范围为0.2至15克/升的悬浮液。还从不同流域收集了浓度范围为0.2至21克/升的径流悬浮液。分别在蔗糖溶液和蒸馏去离子水中测量土壤和径流悬浮液的浊度。蔗糖溶液的密度范围为1.10至1.30千克/升。随着蔗糖溶液密度的增加,浊度降低。在1.30千克/升的蔗糖溶液中,TSS浓度对浊度变化最为敏感。与蒸馏去离子水相比,使用1.30千克/升的蔗糖溶液时,TSS估算的粒径偏差和误差至少降低了20%。悬浮颗粒与蔗糖溶液之间折射率差异的减小,以及颗粒沉降和布朗运动的减弱,共同降低了粒径分布的影响。我们建议使用1.30千克/升的蔗糖溶液作为更好的悬浮介质,以减弱粒径分布的影响,从而提高悬浮液中TSS浓度的估算。