金属配合物中的结构与光学活性，第六章。组氨酸与溶液中铜（II）的相互作用。
Structure and optical activity in metal complexes, vi. Interaction of histidine with copper(ii) in solution.
作者信息
Wellman K M, Wong B K
机构信息
DEPARTMENT OF CHEMISTRY, UNIVERSITY OF MIAMI CORAL GABLES, FLORIDA.
出版信息
Proc Natl Acad Sci U S A. 1969 Nov;64(3):824-7. doi: 10.1073/pnas.64.3.824.
Abstract
The species existing in aqueous solution at pH 8.3 when copper(II) interacts with two equivalents of L-histidine has been studied by a variety of techniques. The evidence is consistent with a fluctuating type of coordination for the histidinato-copper(II) complex, which varies according to conditions and other coordinating ligands involved.
摘要
当铜（II）与两当量的L-组氨酸相互作用时，在pH 8.3的水溶液中存在的物种已通过多种技术进行了研究。证据表明，组氨酸铜（II）配合物存在一种波动类型的配位，其根据条件和所涉及的其他配位配体而变化。
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