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溶液准分子和激发态质子转移情况下四能级激光作用的机制。

Mechanism of four-level laser action in solution excimer and excited-state proton-transfer cases.

机构信息

Department of Chemistry and Institute of Molecular Biophysics, The Florida State University, Tallahassee, Florida 32306.

出版信息

Proc Natl Acad Sci U S A. 1983 Mar;80(6):1767-70. doi: 10.1073/pnas.80.6.1767.

DOI:10.1073/pnas.80.6.1767
PMID:16593295
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC393686/
Abstract

Four-level laser energy level schemes are compared from the mechanistic spectroscopic viewpoint: (i) noble-gas excimer, (ii) solution molecular excimer, (iii) conventional dye laser, and (iv) intramolecular proton transfer. The lasing action of the chlorophyll special pair is discussed as an example of a solution excimer laser, and the lasing action of 3-hydroxyflavone and other molecules is discussed as an example of an intramolecular proton-transfer laser.

摘要

从机制光谱学的角度比较了四能级激光能级方案

(i)稀有气体准分子,(ii)溶液分子准分子,(iii)传统染料激光,和(iv)分子内质子转移。叶绿素特殊对的激光作用被讨论作为溶液准分子激光的一个例子,而 3-羟基黄酮和其他分子的激光作用被讨论作为分子内质子转移激光的一个例子。

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本文引用的文献

1
Photophysical properties of zinc and magnesium tris(pyrochlorophyllide a) 1,1,1-tris(hydroxymethyl)ethane triesters.锌和镁三(焦脱镁叶绿酸 a)1,1,1-三(羟甲基)乙烷三酯的光物理性质。
Proc Natl Acad Sci U S A. 1980 Oct;77(10):5598-601. doi: 10.1073/pnas.77.10.5598.
2
Excited-state two-proton tautomerism in hydrogen-bonded n-heterocyclic base pairs.氢键连接的氮杂环碱基对中的激发态双质子互变异构
Proc Natl Acad Sci U S A. 1969 Jun;63(2):253-60. doi: 10.1073/pnas.63.2.253.