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Theoretical insights into photochemical reactions initiated with circularly polarized light.

作者信息

Pagni Richard M, Bartmess John

机构信息

Department of Chemistry, University of Tennessee, Knoxville, TN 37996-1600, USA.

出版信息

Chirality. 2006 Jun;18(6):419-25. doi: 10.1002/chir.20275.

Abstract

A theoretical analysis of several hypothetical photoreactions initiated with circularly polarized light has been carried out to determine the factors influencing the enantiomeric excess of recovered reactant. The anistropic g value is the dominant influence, although quantum yields and F values may be important in certain cases.

摘要

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