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固体废物热化学特性分析的试点装置

Pilot installation for the thermo-chemical characterisation of solid wastes.

作者信息

Marculescu C, Antonini G, Badea A, Apostol T

机构信息

U. "POLITEHNICA" Bucureşti, Spl. Independentei, 313, Bucureşti, Romania.

出版信息

Waste Manag. 2007;27(3):367-74. doi: 10.1016/j.wasman.2006.02.011. Epub 2006 Apr 17.

Abstract

The increasing production and the large variety of wastes require operators of thermal treatment units to continuously adapt the installations or the functioning parameters to the different physical and chemical properties of the wastes. Usually, the treated waste is encountered in the form of heterogeneous mixtures. The classical tests such as thermogravimetry and calorimetric bomb operate component by component, separately. In addition to this, they can analyse only small quantities of waste at a time (a few grams). These common tests are necessary but insufficient in the global waste analysis in the view further thermal treatment. This paper presents an experimental installation, which was designed and built at the CNRS Science Division, Department of Industrial Methods, Compiègne University of Technology, France. It allows the determination of waste thermal and chemical properties by means of thermal treatment. Also, it is capable of continuously analysing significant quantities of waste (up to 50kg/h) as compared to the classical tests and it can work under various conditions: The installation reproduces the process conditions from incinerators or pyrolysis reactors. It also provides complete information on the kinetics of the waste thermal degradation and on the pollutant emissions. Using different mixtures of components present in the municipal solid waste and also in the reconstituted MSW samples, we defined a series of criteria for characterising waste behaviour during the stages of the main treatment process such as: feeding, devolatilisation/oxidation, advancement, solid residue evacuation, and pollutants emission.

摘要

废物产量的不断增加以及种类的繁多,要求热处理装置的操作人员不断调整设备或运行参数,以适应废物不同的物理和化学性质。通常,待处理的废物以非均质混合物的形式出现。诸如热重分析法和量热弹法等传统测试是逐个对组分进行单独操作的。除此之外,它们每次只能分析少量废物(几克)。这些常规测试对于进一步热处理的整体废物分析而言是必要的,但并不充分。本文介绍了一种实验装置,它是由法国贡比涅技术大学工业方法系法国国家科学研究中心科学部设计并建造的。该装置能够通过热处理来测定废物的热性质和化学性质。此外,与传统测试相比,它能够连续分析大量废物(高达50千克/小时),并且可以在各种条件下运行:该装置再现了焚烧炉或热解反应器的工艺条件。它还提供了有关废物热降解动力学和污染物排放的完整信息。通过使用城市固体废物以及再造城市固体废物样品中存在的不同组分混合物,我们定义了一系列标准,用于表征废物在主要处理过程各阶段的行为,例如:进料、脱挥发分/氧化、推进、固体残渣排出和污染物排放。

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