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纳米多孔配位框架ErIII[CoIII(CN)6].4(H2O)的脱水：ErIII[CoIII(CN)6]中的单晶到单晶转变和负热膨胀

Dehydration of the nanoporous coordination framework ErIII[CoIII(CN)6].4(H2O): single crystal to single crystal transformation and negative thermal expansion in ErIII[CoIII(CN)6].

作者信息

Pretsch Thorsten, Chapman Karena W, Halder Gregory J, Kepert Cameron J

机构信息

School of Chemistry, University of Sydney, Australia.

出版信息

Chem Commun (Camb). 2006 May 7(17):1857-9. doi: 10.1039/b601344a. Epub 2006 Mar 20.

DOI:10.1039/b601344a
PMID:16622507
Abstract

Desorption of bound and unbound water molecules from the nanoporous coordination framework ErIII[CoIII(CN)6].4(H2O) to form the apohost, ErIII[CoIII(CN)6], proceeds via a single crystal to single crystal transformation in which the Er(III) cations change from 8- to 6-coordinate; dehydration results in a striking change in the thermal expansion properties.

摘要

来自纳米多孔配位框架ErIII[CoIII(CN)6].4(H2O)的结合水和未结合水分子的解吸以形成脱辅主体ErIII[CoIII(CN)6]，是通过单晶到单晶的转变进行的，其中Er(III)阳离子从8配位变为6配位；脱水导致热膨胀性质发生显著变化。

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