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A scandium coordination polymer constructed from trimeric octahedral building blocks and 2,5-dihydroxyterephthalate.

作者信息

Dietzel Pascal D C, Blom Richard, Fjellvåg Helmer

机构信息

SINTEF Materials and Chemistry, Postboks 124, Blindern, N-0314, Oslo, Norway.

出版信息

Dalton Trans. 2006 May 7(17):2055-7. doi: 10.1039/b516365j. Epub 2006 Mar 13.

DOI:10.1039/b516365j
PMID:16625248
Abstract

Scandium chloride and nitrate react with 2,5-dihydroxyterephthalic acid to form three-dimensional framework compounds in which hexagonally-closed packed inorganic building blocks are linked by the carboxylate groups of the organic ligand. The inorganic moieties consist of three scandium oxygen octahedra that are joined by a common mu3-oxygen atom; the pores in the structure account for 60% of the volume, but the framework decomposes upon removal of the solvent molecules.

摘要

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